Rare metals handbook

Preparation of rare earth metals

The production of over 400 grams of pure gadolinium metal by reduction of the anhydrous chloride by calcium in tantalum vessels is described; yields were over 97%. The use of the same techniques in an attempt to prepare yttrium metal were partially successful.

The Interaction of Rare Gases with Metals

Interaction potentialsof rare gases withmetal surfaces are calculated and compared with experimental data. A local dielectric function formalism and the density functional method are used in the calculation of the attractive and repulsive energies respectively. Depth and curvature variations of the potentials suggest a classification into light (He, Ne) and heavy rare gases. Sensitivity of the ...

Spin Dependent Transport and Magnetic Ordering in Rare Earth Metals

Elastic and Acoustic Properties of Heavy Rare-Earth Metals

In this paper, ultrasonic properties like ultrasonic attenuation, sound velocities, acoustic coupling constants and thermal relaxation time have been studied in hexagonal structured metals Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er) and Thulium (Tm) along unique axis at room temperature. For the evaluations of ultrasonic properties, secondand thirdorder elastic con...

Molecules containing rare-earth atoms solely bonded by transition metals.

Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids [Ln(ReCp(2))(3)] (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals ...